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Current Highlights

Surprise, Surprise: The Electronic Structure of Linear Coordination Compounds with NHC Ligands

Metal ions in exotic coordination environments represent highly attractive targets in magnetochemistry. We went one step further and looked at under-coordinated (linear) Fe and Co complexes comprising non-innocent ligands. A comparative analysis of the magnetic characteristics, assuming different electron distribution scenarios, revealed Co(II) and Fe(II) centers and NHC radical anions — contrary to the common assumption of M(I) centers in such complexes. See our joint paper with Andreas Danopoulos and Pierre Braunstein in:

A. Danopoulos, P. Braunstein, K. Monakhov, J. van Leusen, P. Kögerler, M. Clémancey, J.-M. Latour, A. Benayad, M. Tromp, E. Rezabal, G. Frison, "Heteroleptic, Two-coordinate [M(NHC){N(SiMe3)2}] (M = Co, Fe) Complexes: Synthesis, Reactivity and Magnetism Rationalized by an Unexpected Metal Oxidation State", Dalton Trans. 2017, 46, 1163-1171 (oa doi:10.1039/C6DT03565E).



True Classical/Non-Classical Polyoxometalate Hybrids: A Radically Novel Point of Departure Towards Single-Molecule Electronics

Multiple, precise contacts to a single molecule represents a technological challenge that is far from trivial. As mentioned earlier, we explore the use of hybrid cluster structures to pre-fabricate the crucial molecule-metal interfaces, ideally with atomic precision. In this context we now present model systems in which classical polyoxometalates (comprising early transition metal addenda atoms) and non-conventional POMs (based on late transition metals) are directly joined, without the need for additional support groups — with the prospect of transforming the latter into metallic nano-structures via element-selective reduction. Identifying reaction conditions commensurate for the formation of both classical and non-conventional POMs and their co-condensation has been termed a "holy grail" of molecular metal oxide chemistry, and is described in:

N.V. Izarova, B. Santiago-Schübel, S. Willbold, V. Heß, P. Kögerler, "Classical/Non-classical Polyoxometalate Hybrids", Chem. Eur. J. 2016, 22, 16052-16056 (oa doi:10.1002/chem.201604238).



Congratulations and Welcome to Our Incoming CSC and HEC Fellows!

Six PhD students funded by the CSC and HEC will join the group this fall:

Shengyang Guan, Tuba Iftikhar, Jinxiu Liu, Sidra Sarwar, Waqas Ali Shah, and Wenyan Wang



Magnetism of Berkelium Coordination Compounds

In comparison to their 4f siblings, the magnetism of actinide ions is highly complex due to the energetic similarity of their single-ion effects. The "full" model Hamiltonian implemented in CONDON enabled, for the first time, the modeling and a precise understanding of the electronic structure of Bk(III) coordination compounds. Such insight will also help improve separation of heavy elements. For this collaboration with Thomas Albrecht-Schmitt (Florida State University) see:

M.A. Silver, S.K. Cary, J.A. Johnson, R.E. Baumbach, A.A. Arico, M. Luckey, M. Urban, J.C. Wang, M.J. Polinski, A. Chemey, G. Liu, K.-W. Chen, S.M. Van Cleve, M.L. Marsh, T.M. Eaton, L.J. van de Burgt, A.L. Gray, D.E. Hobart, K. Hanson, L. Maron, F. Gendron, J. Autschbach, M. Speldrich, P. Kögerler, P. Yang, J. Braley, T.E. Albrecht-Schmitt, "Characterization of berkelium(III) dipicolinate and borate compounds in solution and the solid state", Science 2016, 353, aaf3762 (doi:10.1126/science.aaf3762). Also featured in Chemical & Engineering News.



Magnetism Reveals Bonding Characteristics of 4f and 5f Orbitals

In a comparative study on 4f3 and 5f3 complexes with carefully chosen sets of π- and σ-bonding ligands, spearheaded by Wayne Lukens, we demonstrate that magnetic (susceptibility and EPR spectroscopy) data allows for far-reaching conclusions on the covalent bonding character of the magnetically active f orbitals. See our joint work with several US partner groups:

W. Lukens, M. Speldrich, P. Yang, T.J. Duignan, J. Autschbach, P. Kögerler, "The roles of 4f and 5f orbitals in bonding: a magnetochemical, crystal field and density functional theory-based study", Dalton Trans. 2016, 45, 11508-11521 (oa doi:10.1039/c6dt00634e).



A Critical View on Effective Models and ab initio Simulations in Molecular Magnetism

Prompted by the tremendous feedback we have received, we have made this review freely accessible to anyone.

Zoom Picture

The physical understanding of the microscopic magnetic structure of molecular magnets is often undermined by "effective" approximations that aim to project the quantum mechanical reality of such molecules onto simplified empirical models. While this might lead to deceptively nice-looking fits, the results are often of limited physical meaning, in particular in the case of more anisotropic spin centers. Read more about how such "frankenspin monsters" compare to (more physically sound) "full" model interpretation in:

J. van Leusen, M. Speldrich, H. Schilder, P. Kögerler, "Comprehensive Insight into Molecular Magnetism via CONDON: Full vs. Effective Models", Coord. Chem. Rev. 2015, 289-290, 137-148 (oa doi:10.1016/j.ccr.2014.10.011).



Semimetal Functionalization

... allows us to greatly expand classical polyoxovanadate architectures and to introduce novel physical properties and organic functionalization strategies. We summarize the state-of-the-art of this emerging field of polyoxometalate chemistry in our recent review in:

K.Yu. Monakhov, W. Bensch, P. Kögerler, "Semimetal-functionalised polyoxovanadates", Chem. Soc. Rev. 2015, 44, 8443-8483 (oa doi:10.1039/c5cs00531k).



Open Access Availability

We now aim to provide open access to all of our more recent and upcoming papers. Articles available via "Green" or "Gold" open access models will be marked (oa) in our list of publications.



Congratulations to Kirill!

Dr. Kirill Monakhov has received a prestigious Emmy Noether Fellowship of the Deutsche Forschungsgemeinschaft. His independent Junior Research Group will work on the "Development of Heteropolyvanadate Spin Clusters as Candidates for Future Redox-Based Memory Devices".



Congratulations and Farewell to Claire!

Starting August 2015, Dr. Claire Besson will join the Chemistry Department at George Washington University (Washington, D.C., USA) as a tenure-track assistant professor.

We wish you all the best and a highly successful future!



A Survey on Single-Molecule Magnets based on Polyoxometalates

Polyoxometalates, in particular polyoxomolybdates and -tungstates, provide countless diamagnetic molecular frameworks that we readily can functionalize by integration of spin centers, e.g. paramagnetic transition metal ions. However, only in the past few years have some of these magnetic clusters been identified as single-molecule magnets, meaning that they are characterized by a slowing down of the magnetization relaxation, and possibly even magnetization hysteresis akin to bulk ferromagnets, at low temperatures. We review the current state of affairs in:

N.V. Izarova, P. Kögerler, "Polyoxometalate-based Single-Molecule Magnets", in Trends in Polyoxometalates Research (Eds.: L. Ruhlmann, D. Schaming), Nova Science Publishers, Hauppauge, 2015 (oa get PDF).



High-Valent Iridium Enters Polyoxometalates: A Russian-German Collaboration

The higher oxidation states of iridium are paramount for the role of Ir complexes as promoters or intermediates in oxidation reactions. Yet, the preparative coordination chemistry of Ir(III) and Ir(IV) is notoriously complicated. Jointly with the group of Maxim Sokolov (Novosibirsk) we reconcile the seemingly incompatible aqueous chemistry of iridium cations and tungstates and provide a convenient blueprint for the development of Ir(IV)-based POMs and possibly even Ir(V)-POM chemistry, which promises intriguing electrochemical and catalytic properties. See:

S.A. Adonin, N.V. Izarova, C. Besson, P.A. Abramov, B. Santiago-Schübel, P. Kögerler, V.P. Fedin, M.N. Sokolov, "An Ir(IV)-containing Polyoxometalate", Chem. Commun. 2015, 51, 1222-1225 (oa doi:10.1039/C4CC09271F).



Hypersensitive Polyoxovanadate Spin Clusters

Polyoxovanadate host-guest complexes are known since ages (read: 20 years). Especially mixed-valent species display a pronounced tendency towards structural complementarity, where the shape of the guest determines the host cluster type, despite very weak, purely electrostatic host-guest interactions. A closer look at the {V22O54(X)} family revealed a bunch of surprises linked to the intricate distribution of vanadium 3d electron density and its ultra-sensitive response to perturbations. See:

K.Yu. Monakhov, O. Linnenberg, P. Kozłowski, J. van Leusen, C. Besson, T. Secker, A. Ellern, X. López, J.M. Poblet, P. Kögerler, "Supramolecular Recognition Influences Magnetism in [X@HVIV8VV14O54]6- Self-Assemblies with Symmetry-Breaking Guest Anions", Chem. Eur. J. 2015, 21, 2387-2397 (doi:10.1002/chem.201403858).



Counting on Neodynium for Molecular Spintronics

Quantum charge transport through single-molecule magnets is at the heart of molecular spintronics. However, the magnetically active orbitals need to be at the right energy so that they can actually interact with the electrons tunneling through the molecule. We discovered that early lanthanide ions such as Nd(III) fullfil these requirements. This allows, for the first time, the direct observation of molecular 4f-states by scanning tunneling microscopy. See our work in collaboration with our physics partners at Research Center Jülich:

S. Fahrendorf, N. Atodiresei, C. Besson, V. Caciuc, F. Matthes, S. Blügel, P. Kögerler, D. E. Bürgler, C. M. Schneider, "Accessing 4f-states in Single-Molecule Spintronics", Nature Commun. 2013, 4, 2425 (oa doi:10.1038/ncomms3425).

This work was also highlighted in Nature Nanotechnology (doi:10.1038/nnano.2013.245).





COST Action "Polyoxometalate Chemistry for Molecular Nanoscience" (PoCheMoN) approved

Paul Kögerler will act as Vice Chair for the COST Action CM1203 which aims to consolidate and communicate the efforts in polyoxometalate chemistry in 21 European countries as well as several near-neighbor and international partner countries. The EU-funded Action will run until November 2016.





Stabilization and Control of Fe-Pt Nanoparticles with Polyoxometalates

Magnetic metal nanoparticles of a few nm fill the gap between the magnetism of single or few metal atoms and cooperative phenomena of condensed phases. Yet, the stabilization and the controlled synthesis of mono-disperese ultra-small nanoparticles (less than 5 nm) remain tricky. Fortunately, functionalized polyoxometalates of the Keggin type can stabilize the surface of such nanoparticles, yielding water-soluble core-shell systems. For our results on such POM-nanoparticle hybrids based on technologically important, hard ferromagnetic FePt phases see:

K.M. Seemann, A. Bauer, J. Kindervater, M. Meyer, C. Besson, M. Luysberg, P. Durkin, W. Pyckhout-Hintzen, N. Budisa, R. Georgii, C.M. Schneider, P. Kögerler, "Polyoxometalate-stabilized, water dispersible Fe2Pt magnetic nanoparticles", Nanoscale 2013, 5, 2511-2519 (oa doi:10.1039/c3nr33374d).



Getting Polyoxometalate Nanoreactors to Work

Spherical oxomolybdate clusters of the Keplerate type provide highly defined interior cavities (with a volume of approx. 1.5 nm3) as well as pores. We were able to demonstrate that these systems can indeed function as nanoreactors in which steric confinement translates into specific regioselectivies. At the same time, running an organic cycloaddition reaction within this nanoreactor shields the reactants from catalytically active species in the solution surrounding the Keplerate clusters.

C. Besson, S. Schmitz, K.M. Capella, S. Kopilevich, I.A. Weinstock, P. Kögerler, "A regioselective Huisgen reaction inside a Keplerate polyoxomolybdate nanoreactor", Dalton Trans. 2012, 41, 9852-9854 (doi:10.1039/c2dt30502j).



Prof. Kögerler receives ERC Grant (Consolidator Level) "MOLSPINTRON"

Revolutionary innovations in microelectronics mandate new materials: molecular magnets, used as integral transistor components, are expected to offer several decisive advantages, such as extremely low energy consumption and highly complex switching functions that are hard to realize using conventional semiconductor logic devices. The foundation for these characteristics is the joint utilization of magnetic and electronic quantum states of individual magnetic molecules.

In our ERC project 'Synthetic Expansion of Magnetic Molecules Into Spintronic Devices' (11/2012-10/2017), we aim to tackle one of central difficulties in molecular spin electronics: precise and reproducible contacts of the particle. We utilize highly stable magnetic metal oxide nanomolecules and exploit their versatile surface chemistry. Thus, contacts can be made synthetically, i.e., with atomic precision, creating both conductive and nonconductive interfaces.





Alternative Metal Oxide Cluster Chemistry: The Dark Secrets of Cerium

Classical polyoxometalates are typically based on group 5/6 transition metals (V, Nb, Mo, W). What about their communist left-leaning neighbors with less valence electrons? Surprisingly, high-nuclearity molecular cerium oxides can indeed be formed via controlled condensation reactions. Read how their chemistry and structures mimic that of archetypal polyoxometalates in:

I.L. Malaestean, A. Ellern, S. Baca, P. Kögerler, "Cerium oxide nanoclusters: Commensurate with concepts of polyoxometalate chemistry?", Chem. Commun. 2012, 48, 1499-1501 (doi:10.1039/c1cc14725k).
Full Paper. Heterometallic [Cu2Ln3] (Ln = DyIII, GdIII and HoIII) and [Cu4Ln2] (Ln = DyIII and HoIII) Compounds: Synthesis, Structure, and Magnetism. S. Biswas, P. Bag, S. Das, S. Kundu, J. van Leusen, P. Kögerler, V. Chandrasekhar, Eur. J. Inorg. Chem. 2017, 8, 1129-1142. DOI: 10.1002/ejic.201601210
Review Article. Semimetal-functionalised polyoxovanadates. K.Yu. Monakhov, W. Bensch, P. Kögerler, Chem. Soc. Rev. 2015, 44, 8443-8483. DOI: 10.1039/C5CS00531K
Full Paper. Supramolecular Recognition Influences Magnetism in [X@HVIV8VV14O54]6- Self-Assemblies with Symmetry-Breaking Guest Anions. K.Yu. Monakhov, O. Linnenberg, P. Kozłowski, J. van Leusen, C. Besson, T. Secker, A. Ellern, X. López, J.M. Poblet, P. Kögerler, Chem. Eur. J. 2015, 21, 2387-2397. DOI: 10.1002/chem.201403858
Communication. A polyoxometalate-based single-molecule magnet with an S = 21/2 ground state. X. Fang, P. Kögerler, M. Speldrich, H. Schilder, M. Luban, Chem. Commun. 2012, 48, 1218-1220. DOI: 10.1039/C1CC15520B
Perspective. Structure-related frustrated magnetism of nanosized polyoxometalates: aesthetics and properties in harmony. P. Kögerler, B. Tsukerblat, A. Müller, Dalton Trans. 2010, 39, 21-36. DOI: 10.1039/B910716A

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